Oxygen vacancy-driven orbital multi-channel Kondo effect in Dirac nodal line metals IrO2 and RuO2

The non-symmorphic rutile space group enforces the existence of a network of Dirac nodal lines in the Brillouin zones of transition metal rutiles like RuO2 and IrO2 A recent report published in Nature Communications demonstrates that oxygen vacancies in IrO2 and RuO2 nanowires drive a fragile many-body state known as the orbital Kondo effect.

Crystal structure of transition metal rutiles. Shown is the vicinity of an oxygen vacancy (denoted VO. In IrO2  these vacancies drive an orbital two-channel Kondo effect that leads to a square-root-in-temperature contribution to the resistivity. In RuO2 an orbital one-channel Kondo effect ensues which shows characteristic scaling in temperature and the Kondo energy scale TK over several orders of magnitude.

Interestingly, the symmetries that enforce the existence of DNLs also promote the formation of nonmagnetic Kondo correlations. The demonstration that the non-symmorphic rutile space group supports oxygen-driven orbital Kondo effects in transition metal rutiles holds promise for the realization of novel states of matter and may have ramifications in other materials featuring oxygen vacancies. 

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